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Electrolyte Additive BDIM Enhances Aqueous Zinc Batteries

Electrolyte Additive BDIM Enhances Aqueous Zinc Batteries

On 29 June 2026, researchers at the Institute of Nano Science and Technology (INST), Mohali, reported an electrolyte additive, 1,3-bis(1,3-dicarboxypropyl)-1H-imidazole-3-ium chloride (BDIM), for aqueous zinc‑ion batteries (AZIBs) in ACS Electrochemistry.

Key innovation

  • BDIM (chemical): 1,3-bis(1,3-dicarboxypropyl)-1H-imidazole-3-ium chloride; electrolyte additive developed at INST; published 29 June 2026 in ACS Electrochemistry.
  • Target interface: Selective adsorption on zinc metal surface and regulation of the Inner Helmholtz Plane (IHP).
  • Water displacement: BDIM displaces interfacial water molecules at the zinc–electrolyte boundary.

Electrochemical effects

  • Hydrogen evolution: Suppresses hydrogen evolution reaction (HER) at the zinc interface.
  • Corrosion and dendrites: Reduces zinc corrosion and dendrite nucleation and growth.
  • Cell performance: Improves cycling stability and extends operational lifespan of AZIB cells.

Research methods

  • Diagnostic tools: Laboratory‑developed ultramicroelectrode (UME) combined with fast‑scan cyclic voltammetry (FSCV) to probe zinc‑deposition and interfacial charge‑transfer kinetics.
  • Approach: Interface‑engineering via electrolyte design rather than electrode material redesign.

Applications & relevance

  • Use cases: Grid‑scale storage, renewable energy buffering and backup power where low cost and aqueous safety are priorities.
  • AZIB attribute: Aqueous electrolytes are non‑flammable and zinc is a low‑cost, abundant anode material.

IASPOINT Booster Facts

  • INST status: Autonomous institute under Department of Science & Technology (DST).
  • IHP definition: The region of specifically adsorbed ions and solvent molecules adjacent to the electrode surface where interfacial reactions occur.
  • HER reaction: In acidic/neutral aqueous media, 2H+ + 2e− → H2; a parasitic reaction in AZIBs.
Last Modified: June 30, 2026

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